Right, I haven't decided any weapons yet, as this undertaking took me several hours. It was fun though.

Here are my ideas.
Warriors
Wulfhild: I love the shoulders, but hate that the colours don't match. I love the pauldron model however. Needs revision.
Zulmaka: Happy with this one.
Druids
Lorellin: My favourite set with my favourite headpiece. Gloves and shoes subject to change. Belt needs considering.
Izikii: Sorry about the unsightly squares. Bit undecided on this. I like it, but I don't know if it's really "her".
Elgiva: Rogue tier, so not going to happen.
Sunhaze: Happy with this.
Warlock
Echraide: My heart told me to pick this one, as I've loved this tier always. But it doesn't suit Ech, and without the helmet (which I'd not use no matter how cool), it's not really as awesome as it should be. Many lovely Warlock outfits to pick from, so very much subject to change.
Mage
Ashanaa: Just one of many, many outfits and the one that spoke to me today. Subject to change, and also likely the character that will be dishing out the most money for transmogrification on a regular basis.
Hunters
Mozag: Love the outfit, not sure about it on Mozag. Will probably change.
Lazuli: Her RP outfit, yay! Hate the shoulders though.
Lomelinda: Just can't decide whether I love it, or whether it's just dull. Subject to change.
Alburga: Not as nice as my RP outfit (curse you, leather!), but will do.
Dawnsong: I think most of this is Shammy only, so I can dream on.
Garshanga: It'll do for now. Not in love with it.
Salariel: My Veph tribute plus only Belf I can stand looks perfect in this. Juuust perfect.
Lindorindel: Shammy tier, won't be happening.
Eadgyth: In love with this for my half Dark Iron. :>
Priests
Osharaa: Unimaginitive choice, but I want it mainly for the twisted connotations this brings to her RP story.
Soxie: Another obvious choice, but I've been in love with this forever.
Shaman
Mazakeen: Lots of clashy colours here, but I can't have the actual set I want (tier 3), so this will do for now.
Ushamaa: Love it.
Paladins
Ishalaa: I know, everyone wants this, and I don't even know if it's available. But BOY is it perfect.
Ermentrude: I don't like that her hair doesn't display properly in this outfit, but perhaps I'll survive.
That was fun. Thanks for reading this far, if you bothered.
